Overview for the Nomenclature of Salts, the metal-nonmetal compounds

MEMORIZE the first four tables of this page and you will be proficient in the naming of salts. This is not the complete inorganic nomenclature(!), but what you find here is the minimum requirement for Chem 3A and Chem 1A. For most of you it is a new language and there is a lot to learn here. 

We use two essential tools: 

1. The Periodic Table.

2. Absolute knowledge of the formulas of the five common acids and names directly derived from them, as shown in Table II hereunder. 

Essential is: practice as many examples as you can find in your text book and in Sackheim ("The Red Workbook", Chapter 3).

I. All single negative ions are ending with -ide 

for example: Cl- is chloride, S2- is sulfide, and N3- is nitride.

II. Memorize the Five Common Acids and the negative ions derived from them.

Common Acid Name
Formula

Salts ending with -ate

Salts ending with -ite

Derived from

chloric acid HClO3 chlorate = ClO3- chlorite = ClO2- HClO2 = chlorous acid
nitric acid HNO3 nitrate = NO3- nitrite = NO2- HNO2 = nitrous acid
sulfuric acid H2SO4 sulfate = SO42- sulfite = SO32- H2SO3 = sulfurous acid
carbonic acid H2CO3 carbonate = CO32- N/A N/A
phosphoric acid H3PO4 phosphate = PO43- phosphite= PO33- H3PO3 = phorphorous acid


III. Roman Numerals are used for the charges of some metal ions.

Memorize the Metal Ions that require a Roman Numeral in parenthesis behind their name. They can also be described with -ous and -ic endings behind their Latin name as shown here:


iron(II) = Fe2+= ferrous

iron(III) = Fe3+= ferric

copper(I) = Cu+= cuprous

copper(II) = Cu2+ = cupric

tin (II) = Sn2+ = stannous

tin (IV) = Sn4+= stannic

lead(II) = Pb2+= plumbous

lead (IV) = Pb4+= plumbic

mercury(I) = Hg22+= mercurous

mercury(II) = Hg2+= mercuric

manganese(II) = Mn2+= manganous

manganese(IV) = Mn4+ = N/A

chromium(III) = Cr3+ = chromous

chromium(VI) = Cr6+= chromic
 

Memorize These Complex Ions:


ammonium = NH4+


hydroxide = OH-


cyanide = CN-


peroxide = O22-


permanganate = MnO4-



NO ROMAN Numerals !

Memorize the charges of:


nickel = Ni2+

(nickel (III) is very rare)


cadmium = Cd2+;    zinc = Zn2+


silver = Ag+

(silver (II) is very rare)



IV. The Hydrogen Acid Salts and two more Acids derived from Chlorine.

Memorize these Hydrogen Acid Salt ions:


bisulfide = hydrogensulfide = HS-


bisulfate = hydrogensulfate = HSO4-


bisulfite = hydrogensulfite = HSO3-


bicarbonate = hydrogencarbonate = HCO3-


(mono)hydrogenphosphate = HPO42-


dihydrogenphosphate = H2PO4-


 

Memorize the following chlorine acids and their negative ions:


perchloric acid = HClO4 and perchlorate = ClO4-


hypochlorous acid = HClO and hypochlorite = ClO-




V. Analogies based on the position in the periodic table.

Four examples:

1. As sodium is Na1+ cesium (element # 55) is also 1+ and consequently cesium chlorite = CsClO2


2. Chlorate = ClO3- then bromate = BrO3-, and silver bromate = AgBrO3


3. Selenium is element # 34. Selenate ion = SeO42- because sulfate = SO42-. Manganese(IV) selenate = Mn(SeO4)2


4. Strontium is element # 38. Strontium hypoiodite = Sr(IO)2




Examples or Tables I-IV.

I.

potassium sulfide = K2S

Al2O3 = aluminum oxide


II.

calcium phosphate = Ca3(PO4)2

Ba(NO2)2 = barium nitrite

zinc carbonate = ZnCO3

AlPO3 = aluminum phosphite


III.

ammonium sulfate = (NH4)2SO4

Cu(CN)2 = copper(II) cyanide

iron(II) peroxide = FeO2

Ag3PO4 = silver phosphate


IV.

calcium monohydrogenphosphate = CaHPO4

NaHCO3 = sodium bicarbonate

or sodium hydrogencarbonate