MEMORIZE the first four tables of this page and you will be proficient in the naming of salts. This is not the complete inorganic nomenclature(!), but what you find here is the minimum requirement for Chem 3A and Chem 1A. For most of you it is a new language and there is a lot to learn here.We use two essential tools:
1. The Periodic Table.
2. Absolute knowledge of the formulas of the five common acids and names directly derived from them, as shown in Table II hereunder.
Essential is: practice as many examples as you can find in your text book and in Sackheim ("The Red Workbook", Chapter 3).
I. All single negative ions are ending with -ide
for example: Cl- is chloride, S2- is sulfide, and N3- is nitride.
II. Memorize the Five Common Acids and the negative ions derived from them.
| Formula |
Salts ending with -ate |
Salts ending with -ite |
Derived from | |
| chloric acid | HClO3 | chlorate = ClO3- | chlorite = ClO2- | HClO2 = chlorous acid |
| nitric acid | HNO3 | nitrate = NO3- | nitrite = NO2- | HNO2 = nitrous acid |
| sulfuric acid | H2SO4 | sulfate = SO42- | sulfite = SO32- | H2SO3 = sulfurous acid |
| carbonic acid | H2CO3 | carbonate = CO32- | N/A | N/A |
| phosphoric acid | H3PO4 | phosphate = PO43- | phosphite= PO33- | H3PO3 = phorphorous acid |
III. Roman Numerals are used for the charges of some metal ions.
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Memorize the Metal Ions that require a Roman Numeral in parenthesis behind their name. They can also be described with -ous and -ic endings behind their Latin name as shown here: iron(II) = Fe2+= ferrous iron(III) = Fe3+= ferriccopper(I) = Cu+= cuprous copper(II) = Cu2+ = cuprictin (II) = Sn2+ = stannous tin (IV) = Sn4+= stanniclead(II) = Pb2+= plumbous lead (IV) = Pb4+= plumbicmercury(I) = Hg22+= mercurous mercury(II) = Hg2+= mercuricmanganese(II) = Mn2+= manganous manganese(IV) = Mn4+ = N/Achromium(III) = Cr3+ = chromous chromium(VI) = Cr6+= chromic |
Memorize These Complex Ions: ammonium = NH4+ hydroxide = OH- cyanide = CN- peroxide = O22- permanganate = MnO4- NO ROMAN Numerals ! Memorize the charges of: nickel = Ni2+ (nickel (III) is very rare) cadmium = Cd2+; zinc = Zn2+ silver = Ag+ (silver (II) is very rare) |
IV. The Hydrogen Acid Salts and two more Acids derived from Chlorine.
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bisulfide = hydrogensulfide = HS- bisulfate = hydrogensulfate = HSO4- bisulfite = hydrogensulfite = HSO3- bicarbonate = hydrogencarbonate = HCO3- (mono)hydrogenphosphate = HPO42- dihydrogenphosphate = H2PO4- |
perchloric acid = HClO4 and perchlorate = ClO4- hypochlorous acid = HClO and hypochlorite = ClO- |
V. Analogies based on the position in the periodic table.
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1. As sodium is Na1+ cesium (element # 55) is also 1+ and consequently cesium chlorite = CsClO2 2. Chlorate = ClO3- then bromate = BrO3-, and silver bromate = AgBrO3 3. Selenium is element # 34. Selenate ion = SeO42- because sulfate = SO42-. Manganese(IV) selenate = Mn(SeO4)2 4. Strontium is element # 38. Strontium hypoiodite = Sr(IO)2 |
Examples or Tables I-IV.
I. |